83180-41-0

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 62872-77-9 (E)-3-benzenesulfonyl-2-undecene 
• 62872-76-8 3-benzene sulfonyl 2-heptene E 
• 17049-49-9 octylmagnesium bromide 

Relevant academic research and scientific papers

Couplage mixte entre sulfones vinyliques et reactifs de Grignard en presence de sels de metal de transition: synthese stereoselective d'olefines trisubstituees.

A new cross coupling reaction of vinylic sulphones with Grignard reagents catalyzed by nickel and iron complexes is described.This reaction is stereospecific : trisubstituted olefins of defined stereochemistry are obtained in good yield.

Organic synthesis with sulfones no. XXXV. Iron catalysed condensation and hydrogenolysis of vinylic sulfones with Grignard reagents. A stereoselective synthesis of di- and trisubstituted olefins

Vinylic sulfones are readily available in the E or Z configuration.Condensation with primary Grignard reagents occurs stereospecifically in the presence of iron catalysts, leading to trisubstituted olefins.With secondary Grignards stereospecific hydrogenolysis to 1,2-disubstituted olefins is observed.