83181-15-1Relevant academic research and scientific papers
Studies in Base-Catalyzed Allenic Oxy-Cope Rearrangement: An Expedient Synthesis of Functionalized Bicyclo and - Systems and 3,5-Cycloundecadien-1-one
Balakumar, Arumugham,Janardhanam, Selvasekaran,Rajagopalan, Krishnamoorthy
, p. 5482 - 5486 (2007/10/02)
The base-catalyzed oxy-Cope rearrangement of systems incorporating an allenic ? system was studied.The rearrangement incidentally leads to functionalized bicyclononane 15, bicyclodecanes 6 and 10, and 3,5-cycloundecadien-1-one 20.The effect
O-SILYLATED ENOLATE PHENYLTHIOALKYLATION: A NEW SYNTHESIS OF UNSATURATED 1,5-DICARBONYL COMPOUNDS.
Khan, Hassan A.,Paterson, Ian
, p. 2399 - 2402 (2007/10/02)
The O-silylated enolates of ketones and esters can be phenylthioalkylated by the chlorides (2) and (3) under ZnBr2-catalysis; ozonolysis and subsequent sulphoxide thermolysis then gives the corresponding unsaturated 1,5-dicarbonyl compounds.
