832114-08-6Relevant articles and documents
Ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping
Ilin, Egor A.,Smirnov, Vladimir O.,Volodin, Alexander D.,Korlyukov, Alexander A.,Dilman, Alexander D.
supporting information, p. 7140 - 7142 (2020/07/14)
Compounds bearing ortho-oriented dialkylamino and boryl groups can serve as efficient reagents to trap difluorocarbene leading to zwitterionic ammonium borates featuring N-CF2-B fragments. The reagents are shelf-stable and can be used as mechanistic probe
Stabilization of zwitterionic aryltrifluoroborates against hydrolysis
Wade, Casey R.,Zhao, Haiyan,Gabba?, Franois P.
supporting information; experimental part, p. 6380 - 6381 (2010/10/18)
The presence of a proximal cationic group in zwitterionic aryltrifluoroborates such as o-(Ph2MeP)C6H 4(BF3) stabilizes these compounds against hydrolysis.