832131-69-8Relevant academic research and scientific papers
A boron-based synthesis of the natural product (+)-trans- dihydrolycoricidine
Poe, Sarah L.,Morken, James P.
supporting information; experimental part, p. 4189 - 4192 (2011/06/20)
Diastereoselective diboration results in the highly selective 1,4-dihydroxylation of chiral cyclohexadienes (see scheme). Together with the catalytic enantioselective conjugate allylboration, the diene diboration facilitates the asymmetric synthesis of the cytotoxic agent (+)-trans- dihydrolycoricidine (1). pin=pinacol. Copyright
1,2-Disubstituted cyclohexane nucleosides: Comparative study for the synthesis of cis and trans adenosine analogues
Vi?a, Dolores,Santana, Lourdes,Uriarte, Eugenio,Terán, Carmen
, p. 473 - 478 (2007/10/03)
A new class of adenosine analogues with 1,2-disubstituted carbocycles (with cis and trans stereochemistry) have been synthesized. Construction of the base on the amino group of (±)-cis-(2-aminocyclohexyl)methanol was more efficient than the Mitsunobu cond
