83219-79-8

Basic information

• Product Name: ethyl 2-methyl-3-oxo-2-<(Z)-2-(phenylsulfonyl)vinyl>butanoate
• Synonyms: ethyl 2-methyl-3-oxo-2-<(Z)-2-(phenylsulfonyl)vinyl>butanoate
• CAS NO: 83219-79-8
• Molecular Weight: 310.371
• Mol File: 83219-79-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 2-methyl-3-oxo-2-<(Z)-2-(phenylsulfonyl)vinyl>butanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-methyl-3-oxo-2-<(Z)-2-(phenylsulfonyl)vinyl>butanoate(83219-79-8)
• EPA Substance Registry System: ethyl 2-methyl-3-oxo-2-<(Z)-2-(phenylsulfonyl)vinyl>butanoate(83219-79-8)

Safety Data

• Hazardous Substances Data: 83219-79-8(Hazardous Substances Data)

Upstream product

• 609-14-3 2-acetylpropanoic acid ethyl ester 
• 32501-93-2 1-(Phenylsulfonyl)-2-(trimethylsilyl)acetylene 

Downstream Products

• 5837-78-5 Ethyl tiglate 
• 83219-96-9 ethyl 3-cyano-2-methyl-2-<(Z)-2-(phenylsulfonyl)vinyl>-3-(trimethylsiloxy)butanoate 

Relevant articles and documents

Phenyl 2-(Trimethylsilyl)ethynyl Sulfone as a New Vinyl Cation Synthon

Phenyl 2-(trimethylsilyl)ethynyl sulfone (PhSO2CCSiMe3, 1) is provided as a new vinyl cation synthon for an efficient introduction of the vinyl group to a variety of carbanionic nucleophiles (see Table I), including a highly hindered one, 29, an important precursor for the synthesis of Aspidosperma alkaloids.Another attractive feature of this reagent, which can be easily prepared in a large scale, is particularly demonstrated by its utility under rather strong basic conditions such as NaH, t-BuOK, KF, etc.