83242-31-3

Basic information

• Product Name: (R)-2-[(2R,3R)-2-(Benzothiazol-2-yldisulfanyl)-4-oxo-3-(2-phenoxy-acetylamino)-azetidin-1-yl]-3-chloromethyl-but-3-enoic acid benzyl ester
• Synonyms: (R)-2-[(2R,3R)-2-(Benzothiazol-2-yldisulfanyl)-4-oxo-3-(2-phenoxy-acetylamino)-azetidin-1-yl]-3-chloromethyl-but-3-enoic acid benzyl ester
• CAS NO: 83242-31-3
• Molecular Weight: 640.205
• Mol File: 83242-31-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-2-[(2R,3R)-2-(Benzothiazol-2-yldisulfanyl)-4-oxo-3-(2-phenoxy-acetylamino)-azetidin-1-yl]-3-chloromethyl-but-3-enoic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-[(2R,3R)-2-(Benzothiazol-2-yldisulfanyl)-4-oxo-3-(2-phenoxy-acetylamino)-azetidin-1-yl]-3-chloromethyl-but-3-enoic acid benzyl ester(83242-31-3)
• EPA Substance Registry System: (R)-2-[(2R,3R)-2-(Benzothiazol-2-yldisulfanyl)-4-oxo-3-(2-phenoxy-acetylamino)-azetidin-1-yl]-3-chloromethyl-but-3-enoic acid benzyl ester(83242-31-3)

Safety Data

• Hazardous Substances Data: 83242-31-3(Hazardous Substances Data)

Upstream product

• 33405-92-4 2-benzothiazolylsulfenyl chloride 
• 70379-78-1 (R)-3-chloromethyl-2-((1R)-7-oxo-3-phenoxymethyl-(1rH,5cH)-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-but-3-enoic acid benzyl ester 

Downstream Products

• 83242-38-0 (6R,7R)-3-(Benzothiazol-2-ylsulfanylmethyl)-8-oxo-7-(2-phenoxy-acetylamino)-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzyl ester 

Relevant articles and documents

PENICILLIN-CEPHALOSPORIN CONVERSION IV. DIRECT SYNTHESIS OF 3'-THIOSUBSTITUTED CEPHALOSPORINS FROM THIAZOLE-AZETIDINONES

Direct transformation of thiazoline-azetidinones 2, derived from penicillin G and V, into 3'-thio-substituted cephalosporins 4 has been performed by ring opening of the thiazoline moiety with sulfenyl chlorides followed by ring closure with NH3 in dimethy