832731-53-0Relevant articles and documents
Kinetic and theoretical study of 4-exo ring closures of carbamoyl radicals onto C=C and C=N bonds
DiLabio, Gino A.,Scanlan, Eoin M.,Walton, John C.
, p. 155 - 158 (2007/10/03)
(Chemical Equation Presented) Carbamoyl radicals were generated from oxime oxalate amides, and the kinetics of their 4-exo cyclizations onto C=C and C=NO bonds, leading to β-lactam-containing species, were studied by EPR spectroscopy. DFT computations wit
Reaction of polychloroacetamides with amines: Reductive dechlorination and aziridine formation
Naito, Takeaki,Saito, Ayako,Ueda, Masafumi,Miyata, Okiko
, p. 1857 - 1869 (2007/10/03)
Treatment of trichloroacetamides with amines undergoes reductive dechlorination via single-electron transfer process to afford dichloroacetamides in good yields. Reaction of trichloro- and dichloroacetamides with DBU provides a new synthetic method of azi