83283-93-6

Upstream product

• 83283-90-3 Cyclopent-1-enecarboxylic acid (2-hydroxy-phenyl)-((2E,4E)-6-methyl-hepta-2,4-dienyl)-amide 
• 94453-21-1 (E),(E)-1-bromo-6-methylhepta-2,4-diene 

Relevant academic research and scientific papers

STEREOSELECTIVE INTRAMOLECULAR DIELS-ALDER REACTIONS OF alpha , beta -UNSATURATED AMIDES USING INTERNAL COORDINATION OF METAL SALTS.

The intramolecular Diels-Alder reactions between acyclic dienes and alpha , beta -unsaturated amides utilizing the internal coordination of the metal salts have been studied in detail. When the magnesium salts of N-(trans, trans-2,4-alkadienyl)-N-(2-hydro

AN EFFICIENT METHOD FOR THE STEREOSELECTIVE SYNTHESIS OF TRICYCLIC COMPOUNDS THE INTRAMOLECULAR DIELS-ALDER REACTION OF CYCLIC α,β-UNSATURATED CARBOXAMIDES

An efficient method for the stereoselective syhthesis of tricyclic compounds was studied by the intramolecular Dields-Alder reaction utilizing the internal coordination of the magnesium salt.The magnesium salts of N-(2,4-alkadienyl)-N-(2-hydroxyphenyl)cyclopent-1-enecarboxamides afford predominantly trans-fused cycloadducts via exo-mode of cyclization.