83293-82-7Relevant academic research and scientific papers
INVESTIGATION IN THE REGION OF UNSATURATED COMPOUNDS. XIV. PRODUCTS FROM LOW-TEMPERATURE CHLORINATION OF 1,2,3-TRICHLORO-2-BUTENE IN THE PRESENCE OF FERRIC CHLORIDE AND TERT-BUTYLPYROCATECHOL
Kaplanyan, E. E.,Mkrtchyan, A. M.,Mkryan, G. M.
, p. 866 - 868 (2007/10/02)
1,2,2,3,3-Pentachlorobutane and 2,3,3,4-tetrachloro-1-butene are formed during the low-temperature (-20 to 25 deg C) chlorination of cis- and trans-1,2,3-trichloro-2-butenes in the presence of anhydrous ferric chloride and tert-butylpyrocatechol.Chlorination is accompanied by isomerization of the 2,3,3,4-tetrachloro-1-butene to 1,2,3,4-tetrachloro-2-butene and also by the addition of chlorine to the tetrachlorobutenes with the formation of 1,2,2,3,3,4-hexachlorobutane.
INVESTIGATION IN THE FIELD OF UNSATURATED COMPOUNDS. XII. BEHAVIOUR OF 2,3-DIHALOGENO-2-BUTENES DURING LIQUID-PHASE CHLORINATION IN THE PRESENCE OF AN INHIBITOR OF RADICAL REACTION
Kaplanyan, E. E.,Mkryan, G. G.,Adamyan, A. P.,Mkryan, G. M.
, p. 2014 - 2020 (2007/10/02)
Both normal addition products (tetrahalogenobutanes) and anomalous reaction products (2,3,3-trihalogeno-1-butenes) are formed during the liquid-phase chlorination of 2,3-dihalogeno-2-butenes (2,3-dichloro-, 2-chloro-3-bromo-, and 2,3-dibromo-2-butenes) in the presence of an inhibitor of radical reactions.Below 20 deg C the cis isomers are chlorinated more rapidly than the trans isomers, mainly forming the anomalous reaction products.During chlorination above 20 deg C (20-40 deg C) the process is complicated by the partial isomerization of the 2,3,3-trihalogeno-1-butene which forms into 1,2,3-trihalogeno-2-butene and, in the case of the bromine-substituted butenes, by substitution of the bromine atom by chloring.
