83299-45-0

Basic information

• Product Name: {(C₄H₉)3PCH₂C₆H₅}⁽¹⁺⁾*{FeCl₄}^(1-)={(C₄H₉)3PCH₂C₆H₅}{FeCl₄}
• CAS NO: 83299-45-0
• Molecular Weight: 491.112
• Mol File: 83299-45-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(C₄H₉)3PCH₂C₆H₅}⁽¹⁺⁾*{FeCl₄}^(1-)={(C₄H₉)3PCH₂C₆H₅}{FeCl₄}(CAS DataBase Reference)
• NIST Chemistry Reference: {(C₄H₉)3PCH₂C₆H₅}⁽¹⁺⁾*{FeCl₄}^(1-)={(C₄H₉)3PCH₂C₆H₅}{FeCl₄}(83299-45-0)
• EPA Substance Registry System: {(C₄H₉)3PCH₂C₆H₅}⁽¹⁺⁾*{FeCl₄}^(1-)={(C₄H₉)3PCH₂C₆H₅}{FeCl₄}(83299-45-0)

Safety Data

• Hazardous Substances Data: 83299-45-0(Hazardous Substances Data)

Upstream product

• 16950-17-7 tetrachloroferrate(III) acid 
• 1224-56-2 tributylbenzylphosphonium chloride 

Relevant articles and documents

1H-NMR- AND MOESSBAUER INVESTIGATIONS ON THE ION PAIRS OF TETRACHLOROFERRATE(III) ANION WITH QUATERNARY PHOSPHONIUM CATIONS

Paramagnetic ion pairs were investigated by 1H-NMR and Moessbauer spectroscopy in chloroform and dimethyl sulphoxide.It has been shown that the chemical shifts of 1H-NMR peaks arise from a combination of contact and pseudocontact interactions of opposite sign, and the ratio of interactions was definitely influenced by the extent of solvation.On the basis of Moessbauer measurements it was shown that the change of the cation size had an effect on the electron delocalization and symmetry conditions of iron(III) in solid samples, too.In concentrated frozen solutions of ion pairs, different interactions were indicated by Moessbauer spectros copy in chloroform and dimethyl sulphoxide, in accordance with 1H-NMR results.However, in dilute solution such an anion-solvent interaction was observed directly, which could be shown by the NMR method only indirectly.