83305-63-9Relevant academic research and scientific papers
α-Arylation of Carbonyl Compounds through Oxidative C?C Bond Activation
Li, Jing,Bauer, Adriano,Di Mauro, Giovanni,Maulide, Nuno
, p. 9816 - 9819 (2019)
A synthetically useful approach for the direct α-arylation of carbonyl compounds through a novel oxidative C?C bond activation is reported. This mechanistically unusual process relies on a 1,2-aryl shift and results in all-carbon quaternary centers. The transformation displays broad functional-group tolerance and can in principle also be applied as an asymmetric variant.
AMMONIUM SALTS IN ALKYLATION. XVIII. ALKYLATION OF ACETOACETAMIDES
Torosyan, G. O.,Gekchyan, G. G.,Babayan, A. T.
, p. 1423 - 1426 (2007/10/02)
Acetoacetamides are alkylated under the conditions of interphase catalysis (liquid-liquid, solid-liqiud) with the formation of high yields of α-alkylacetamides.
