833447-41-9Relevant articles and documents
Room temperature dynamic polymers based on Diels-Alder chemistry
Reutenauer,Buhler,Boul,Candau,Lehn
, p. 1893 - 1900 (2009)
Dynamers based on reversible Diels-Alder chemistry have been obtained and shown to undergo dynamic exchange at room temperature. Their study in solution by small-angle neutron scattering indicated the formation of long and highly flexible chains. Polydispersed molecules gave Tg values below room temperature, permitting the generation of a dynamic elastomer upon introduction of a dynamic cross-linking agent. The use of a system with a low equilibrium constant gives access to materials with interesting self-healing properties.
