83350-49-6

Basic information

• Product Name: C₅H₅Fe(CO)2CH₂CHCHCOCH(C₆H₅)2
• Synonyms: C₅H₅Fe(CO)2CH₂CHCHCOCH(C₆H₅)2
• CAS NO: 83350-49-6
• Molecular Weight: 412.268
• Mol File: 83350-49-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₅H₅Fe(CO)2CH₂CHCHCOCH(C₆H₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: C₅H₅Fe(CO)2CH₂CHCHCOCH(C₆H₅)2(83350-49-6)
• EPA Substance Registry System: C₅H₅Fe(CO)2CH₂CHCHCOCH(C₆H₅)2(83350-49-6)

Safety Data

• Hazardous Substances Data: 83350-49-6(Hazardous Substances Data)

Upstream product

• 38960-10-0 allyl(cyclopentadienyl)iron(II) dicarbonyl 
• 525-06-4 diphenyl ketene 

Relevant articles and documents

[3 + 2] cyclopentane annulation reactions using organoiron reagents

The allyl ligand in the organoiron complex 1, (η1-allyl)Fp [Fp = (η5-C5H5)Fe(CO)2], serves as a C3 dipolar synthon in aluminum bromide catalyzed reactions with cyclohexenone and by itself with 2-carbethoxy-cycloalkenones, affording cyclopentane annulation products. The structural limitations of these reactions with respect to substitution of the enone and the organometallic reagent have been examined. The acetylenic ligand in (η1-2-butynyl)Fp similarly underdoes aluminum bromide catalyzed [3 + 2] cycloaddition reaction with cyclohexenone, but (η1-1-propynyl)Fp yields instead the product of [2 + 2] cycloaddition.