83356-16-5Relevant academic research and scientific papers
Potassium carbamoyldicyanomethanide
Schlueter, John A.,Geiser, Urs
, p. m10-m12 (2004)
The crystal structure of potassium carbamoyldicyano-methanide was investigated. The K atoms were coordinated to four nitrile N atoms and two carbonyl O atoms in a distorted trigonal prismatic fashion, with two further N atoms semicoordinated through the centers of two prism side faces. This coordination led to the formation of mixed anion-cation sheets parallel to the ab plane, which were joined together via hydrogen-bonding interactions. The results show that that the carbamoyldicyanomethanide anion is potentially useful for the formation of transition metal coordination polymers.
