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Thioketene Syntheses, VI. Stable Thioketenes via Thionation of Sterically Hindered Acyl Chlorides
Schaumann, Ernst
, p. 2755 - 2765 (2007/10/02)
Sterically hindered acyl chlorides 11 are accessible via alkylation of the ester 1 or via chain elongation of the ketones 4 by one carbon atom in practicable, though multi-step reaction sequences.Action of phosphorus pentasulfide/pyridine on 11 leads to t
