83357-95-3Relevant academic research and scientific papers
On the Chemistry of (Trifluoromethyl)sulfinylamine, CF3NSO, and Related Compounds
Leidinger, Walter,Sundermeyer, Wolfgang
, p. 2892 - 2897 (2007/10/02)
CF3NSF2 (1) reacts with PCl5 to yield CF3NSCl2 (2) which is converted to the title compound 4 with Ag2O as is well known. 4 can also be obtained from CF3NCl2 (3) and SOCl2, and it reacts with XeF2 to form CF3NSOF2 (5) and with HCl to yield CF3NH2 (6).All reactions were also carried out with the corresponding C2F5 compounds (1a - 6a).The hydrochloride of 6a decomposes via (C2F5)2NH * HCl (11) yielding CF3CF2 - N = CFCF3 (13) in contrast to 6a, which forms CF3CN (14).CF3 - NSN - CF3 (8) can be obtained directly from 4 or from 2 and 3 or 2 and 6, respectively.CF3 - NSN - C2F5 (9) and C2F5 - NSN - C2F5 (10) are formed in the reaction of 2a with 6. 1 reacts with BBr3 to form (trifluoromethyl)imidosulfur dibromide (7).
