83420-48-8

Upstream product

• 120236-44-4 (R)-(-)-4,4-dimethyl-3-(p-diethoxyphosphinoxyphenyl)pentan-2-ol 
• 120236-39-7 (S)-(+)-3,3-dimethyl-2-(p-methoxyphenyl)butanoic acid 
• 120236-38-6 (S)-(+)-1-cyano-2,2-dimethyl-1-(p-methoxyphenyl)propane 
• 120236-43-3 (R)-(-)-4,4-dimethyl-3-(p-hydroxyphenyl)pentan-2-ol 
• 120236-41-1 (R)-(-)-3,3-dimethyl-2-(p-hydroxyphenyl)butanoic acid 
• 120236-42-2 (R)-(-)-4,4-dimethyl-3-(p-hydroxyphenyl)pentan-2-one 
• 120236-37-5 (R)-(+)-2,2-dimethyl-1-(p-methoxyphenyl)propyl chloride 
• 61986-69-4 (-)-(S)-1-(4-methoxyphenyl)-2,2-dimethylpropan-1-ol 
• 120328-80-5 (R)-(+)-2,2-dimethyl-1-(p-methoxyphenyl)propanol 
• 91561-63-6 2,2-dimethyl-1-(p-methoxyphenyl)propyl chloride 
• 23406-58-8 (R)-(-)-4,4-dimethyl-3-phenylpentan-2-one 

Downstream Products

• 23406-58-8 (R)-(-)-4,4-dimethyl-3-phenylpentan-2-one 

Relevant academic research and scientific papers

Cram's Rule for Radical Reactions

Addition of tris(trimethylsilyl)silyl radicals to chiral ketones 1 yields tert. carbon centered radicals 4 that give predominantly Cram products in hydrogen atom abstraction reactions.Analogous sec. acyloxyalkyl radicals undergo radical C,D- and C,C-bond forming reactions that also follow Cram's rule.

Retentive Solvolysis. Part 14. The Methanol-perturbed Phenolysis of Optically Active 2,2-Dimethyl-1-(p-methoxyphenyl)propyl p-Nitrobenzoate. The Mechanism and the Structure of the Second Ion-pair Intermediate

The polarimetric and titrimetric rate constants have been measured for the solvolysis of optically active 2,2-dimethyl-1-(p-methoxyphenyl)propyl p-nitrobenzoate (ROPNB) in phenol-methanol (97:3 w/w).The salt effect of added (Bun)4NClO4 indicate