83451-46-1Relevant academic research and scientific papers
Deoxygenation of Allylic Carbinolamides and Related Alcohols by Acidic Sodium Cyanoborohydride: Scope and Limitations
Drage, James S.,Earl, Richard A.,Vollhardt, K. Peter C.
, p. 701 - 702 (2007/10/02)
Acidic sodium cyanoborohydride reduces allylic and other substituted carbinolamides to the corresponding deoxygenated compounds, whereas other similar alcohols are unreactive or undergo alternative transformations.
ON THE SYNTHETIC UTILITY OF THERMALLY GENERATED IMINES: THE RETRO-ENE IMINO DIELS-ALDER REACTION
Earl, Richard A.,Vollhardt, K. Peter C.
, p. 265 - 271 (2007/10/02)
The flash vacuum pyrolysis of several allyl and propargyl amines provides a preparatively useful synthesis of imines by retro-ene fragmentation.Their synthetic potential is indicated by intramolecular Diels-Alder trapping to give indolizidines in a novel ring-expansion sequence.
