83470-17-1

Basic information

• Product Name: 2-chloro-cis-4-(diphenylphosphinoethylamino)-1,3-di-t-butylcyclodiphosph(III)azane
• CAS NO: 83470-17-1
• Molecular Weight: 467.898
• Mol File: 83470-17-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-chloro-cis-4-(diphenylphosphinoethylamino)-1,3-di-t-butylcyclodiphosph(III)azane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-cis-4-(diphenylphosphinoethylamino)-1,3-di-t-butylcyclodiphosph(III)azane(83470-17-1)
• EPA Substance Registry System: 2-chloro-cis-4-(diphenylphosphinoethylamino)-1,3-di-t-butylcyclodiphosph(III)azane(83470-17-1)

Safety Data

• Hazardous Substances Data: 83470-17-1(Hazardous Substances Data)

Upstream product

• 24335-35-1 cis-1,3-di-tert-butyl-2,4-dichloro-1,3,2,4-diazadiphosphetidine 
• 41391-96-2 diphenylphosphinoethylamine 

Relevant articles and documents

Synthesis and Conformational Studies of (Diphenylphosphinoamino)-cyclodiphosph(III)azanes

A series of 2,4-bis(diphenylphosphinoalkylamino)-1,3-di-t-butylcyclodiphosph(III)azanes, t>2 i or But (cis-isomers)>, have been prepared by the reactions of N-lithiated alkyl-N-(diphenylphosphino)amines, N(PPh2)(R)(Li), with 2-cis-4-dichloro-1,3-di-t-butylcyclodiphosph(III)azane, (ClPNBut)2, in benzene solution.Hydrogen-1, 13C, and 31P n.m.r. spectroscopy show that these compounds are cyclodiphosph(III)azanes rather than phosph(III)azanes, (Ph2P)RNP=NBut, in solution, and variable temperature 31P n.m.r. date have enabled the preferred conformations of the exo-P-N-P skeletons to be identified.In the case of t>2 (R=Pri and But) more than one conformer can be distinguished at sub-ambient temperatures.