83475-70-1

Basic information

• Product Name: [Co((C6H3Me2-3,5)2N4)(η5-C5H5)]
• CAS NO: 83475-70-1
• Molecular Weight: 390.434
• Mol File: 83475-70-1.mol

Chemical Properties

• CAS DataBase Reference: [Co((C6H3Me2-3,5)2N4)(η5-C5H5)](CAS DataBase Reference)
• NIST Chemistry Reference: [Co((C6H3Me2-3,5)2N4)(η5-C5H5)](83475-70-1)
• EPA Substance Registry System: [Co((C6H3Me2-3,5)2N4)(η5-C5H5)](83475-70-1)

Safety Data

• Hazardous Substances Data: 83475-70-1(Hazardous Substances Data)

Upstream product

• 83475-71-2 [Co((C6H4Me-4)2N4)(η5-C5H5)] 
• 70334-59-7 1-azido-3,5-dimethylbenzene 

Relevant articles and documents

Inter- and Intra-molecular Ligand-exchange and -rearrangement Reactions of Tetra-azadiene Complexes of Nickel, Platinum, and Cobalt

Tetra-azadiene-exchange and -rearrangement reactions have been observed for both and 5-C5H5)> (R2=1,4-diaryl) complexes.The reactions of or 5-C5H5)> with aryl azides lead to substitution of the tetra-azadiene ligands.Reactions of or 5-C5H5)> with aryl azides R'N3 produced platinium and nickel complexes with non-symmetrical RN4R' ligands.All products arising from these reactions were identified by field desorption mass spectrometry and/or h.p.l.c.Four mechanisms which can account for the nature of the observed products, the product distributions, and reaction times are discussed.Transient aryl-nitrene species are proposed as key intermediates in these reactions.