83477-69-4Relevant academic research and scientific papers
Preparation method of vinylcyclohexane
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Paragraph 0022-0027, (2021/04/29)
The invention discloses a preparation method of vinylcyclohexane, and belongs to the technical field of organic synthesis. Cyclohexyl ketone is used as a raw material, and is firstly condensed with 2, 4, 6-triisopropylbenzenesulfonyl hydrazide to obtain 1-acetocyclohexane-2, 4, 6-triisopropylbenzenesulfonyl hydrazone; and reaction is carried out in the presence of an inorganic base and a non-nucleophilic strong base to obtain vinylcyclohexane. The method has the advantages of two-step reaction, simple route, high area selection and relatively easy product separation, and a certain amount of polymerization inhibitor needs to be added in the product distillation process to prevent polymerization in the distillation process.
