834868-05-2Relevant academic research and scientific papers
Crystal structure of the bis[zinc(II)-hydroxide-(μ-perchlorate)-triaqua] complex
Li, Yong-Hua,Ye, Qiong,Tang, Yun-Zhi,Xiong, Ren-Gen
, p. 1553 - 1554 (2004)
Colorless single crystals of the title compound were accidentally obtained by a reaction of p-sulfophenylalanine with zinc perchlorate. The crystal structure (monoclinic, P21/c, Z = 4, a = 5.9031(7), b = 13.5404(16), c = 9.7932(8) A, β = 126.438(5)°, V = 629.74(12) A3, R1[I>2σ(I)] = 0.0276, wR 2(all) = 0.0844) reveals a discrete dinuclear [Zn(OH)(μ-ClO 4)(H2O)3]2 in which each perchlorate anion acts as a bidentate bridging linker to bind two Zn atoms whereas the hydroxy group is a terminal group. Thus, the local surrounding around the zinc atom can be best described as a slightly distorted octahedron.
