834894-31-4Relevant academic research and scientific papers
Ligand-accelerated Cu-catalyzed azide-alkyne cycloaddition: A mechanistic report
Rodionov, Valentin O.,Presolski, Stanislav I.,Diaz, David Diaz,Fokin, Valery V.,Finn
, p. 12705 - 12712 (2008/03/14)
The experimental rate law for the Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction was found to vary in complex ways with concentration, the presence of chloride ion, and the presence of accelerating ligands. Several examples of discontinuous (
Mechanism of the ligand-free CuI-catalyzed azide-alkyne cycloaddition reaction
Rodionov, Valentin O.,Fokin, Valery V.,Finn
, p. 2210 - 2215 (2007/10/03)
(Chemical Equation Presented) A powerful engine: The Cu-catalyzed azide-alkyne cycloaddition depends on rapid formation of CuI- acetylide complexes from terminal alkynes 2 and their ability to activate organic azides 1. A kinetics study uncover
