834917-11-2

Upstream product

• 994-30-9 triethylsilyl chloride 
• 834916-73-3 (E)-(4S,5R)-2-Allyl-4,5-dihydroxy-5-((2R,4R,5R)-5-hydroxy-2-phenyl-[1,3]dioxan-4-yl)-pent-2-enoic acid methyl ester 
• 95561-65-2 Triphenylphosphin-allyl-methoxycarbonyl-methylen 
• 3006-41-5 4,6-O-benzylidene-D-glucose 
• 834916-74-4 (E)-(4S,5S)-2-Allyl-5-(4-methoxy-benzyloxymethoxy)-5-((2R,4S,5R)-2-phenyl-5-triethylsilanyloxy-[1,3]dioxan-4-yl)-4-triethylsilanyloxy-pent-2-enoic acid methyl ester 

Downstream Products

• 834916-79-9 Methanesulfonic acid (E)-(6S,7S)-1-((2S,3R)-2,3-dimethyl-4-triisopropylsilanyloxy-butyl)-7-(4-methoxy-benzyloxymethoxy)-4-methoxymethoxymethyl-7-((2R,4S,5R)-2-phenyl-5-triethylsilanyloxy-[1,3]dioxan-4-yl)-6-triethylsilanyloxy-hept-4-enyl ester 
• 834916-76-6 (E)-(6S,7S)-7-(4-Methoxy-benzyloxymethoxy)-4-methoxymethoxymethyl-7-((2R,4S,5R)-2-phenyl-5-triethylsilanyloxy-[1,3]dioxan-4-yl)-6-triethylsilanyloxy-hept-4-en-1-ol 
• 834916-77-7 (E)-(6S,7S)-7-(4-Methoxy-benzyloxymethoxy)-4-methoxymethoxymethyl-7-((2R,4S,5R)-2-phenyl-5-triethylsilanyloxy-[1,3]dioxan-4-yl)-6-triethylsilanyloxy-hept-4-enal 
• 834916-75-5 (2R,4S,5R)-4-[(E)-(1S,2S)-1-(4-Methoxy-benzyloxymethoxy)-4-methoxymethoxymethyl-2-triethylsilanyloxy-hepta-3,6-dienyl]-2-phenyl-5-triethylsilanyloxy-[1,3]dioxane 

Relevant academic research and scientific papers

A formal total synthesis of (+)-pinnatoxin A

Powerful dithiane coupling (A) of two fragments and subsequent macrocyclization by ring-closing metathesis (B) produced the entire 27-membered carbocycle of (+)-pinnatoxin A (1), a major toxic principle responsible for outbreaks of shellfish poisonings in