83497-35-2Relevant academic research and scientific papers
Syntheses of 6-Deoxyhex-5-enopyranosides from 6-Bromo-6-deoxy- or 6-O-p-Tolylsulfonylhexopyranosides by the Use of DBU in DMSO
Sato, Ken-ichi,Kubo, Noriyuki,Takada, Ritsuko,Sakuma, Shogo
, p. 1156 - 1165 (2007/10/02)
Various kinds of nonbranched and methyl-branched 6-deoxyhex-5-enopyranoside derivatives were prepared from 6-bromo-6-deoxy or 6-O-p-tolylsulfonylhexopyranoside in a one-pot procedure by a successive treatment with iodide anion and 1,8-diazabicyclou
Convenient Synthesis of Hex-5-enopyranosides
Sato, Ken-ichi,Kubo, Noriyuki,Takada, Rituko,Aqeel, Amjad,Hashimoto, Hironobu,Yoshimura, Juji
, p. 1703 - 1704 (2007/10/02)
Hex-5-enopyranosides were prepared in an one-pot procedure from 6-bromo-6-deoxy- or 6-O-tosylhexopyranoside by the successive treatment with iodide anion and 1,8-diazabicycloundec-7-ene in DMSO.
BRANCHED-CHAIN SUGARS. XXXV. THE SYNTHESIS OF L-RUBRANITROSE (2,3,6-TRIDEOXY-3-C-METHYL-4-O-METHYL-3-NITRO-L-XYLO-HEXOPYRANOSE).
Yoshimura,Yasumori,Kondo,Sato
, p. 2535 - 2537 (2007/10/02)
The compound was stereoselectively synthesized from methyl 2,6-dideoxy-4-O-methyl- beta -L-threo-hexopyranosid-3-ulose through the successive conversions; cyanomesylation, reductive spiro aziridine formation, reductive ring-opening to the methyl-branched amino sugar, oxidation to the corresponding nitro sugar.
