83548-13-4Relevant academic research and scientific papers
SYNTHESIS OF 2-NITROALKYL PHENYL SELENIDES AND THEIR CONVERSION TO NITROALKENES
Hayama, Takashi,Tomoda, Shuji,Takeuchi, Yoshito,Nomura, Yujiro
, p. 1109 - 1112 (2007/10/02)
Treatment of alkenes with benzeneselenenyl bromide followed by addition of silver nitrite provided a mixture of 2-nitroalkyl and 2-hydroxyalkyl phenyl selenides.Oxidation of the former selenides with hydrogen peroxide gave nitroalkenes in 90-93 percent yields.
SYNTHESIS OF CONJUGATED NITROALKENES VIA NITROSELENENYLATION OF ALKENES
Hayama, Takashi,Tomoda, Shuji,Takeuchi, Yoshito,Nomura, Yujiro
, p. 4733 - 4734 (2007/10/02)
Addition of silver nitrite to 2-bromoalkyl phenyl selenide in the presence of mercury(II)chloride afforded 2-nitroalkyl phenyl selenide, wich upon oxidative deselenenylation provided the conjugated nitroalkene in excellent yield.
