83553-86-0

Basic information

• Product Name: (E)-N-(2,2-Dimethylpropyl)-2,2-dimethyl-1-cyclopropanimin
• Synonyms: (E)-N-(2,2-Dimethylpropyl)-2,2-dimethyl-1-cyclopropanimin
• CAS NO: 83553-86-0
• Molecular Weight: 153.268
• Mol File: 83553-86-0.mol

Chemical Properties

• CAS DataBase Reference: (E)-N-(2,2-Dimethylpropyl)-2,2-dimethyl-1-cyclopropanimin(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-(2,2-Dimethylpropyl)-2,2-dimethyl-1-cyclopropanimin(83553-86-0)
• EPA Substance Registry System: (E)-N-(2,2-Dimethylpropyl)-2,2-dimethyl-1-cyclopropanimin(83553-86-0)

Safety Data

• Hazardous Substances Data: 83553-86-0(Hazardous Substances Data)

Upstream product

• 107769-06-2 1-(2,2-Dimethylpropyl)-4,5-dihydro-4,4-dimethyl-5-methylen-1H-1,2,3-triazol 

Relevant articles and documents

Gas-Phase Thermolysis of Pyrazolines, 3. - Electronic Structure and Gas-Phase Pyrolysis of 4-Substituted 3,5,5-Trialkyl-3,5-dihydro-4H-1,2,3-triazoles Studied by Photoelectron Spectroscopy and Semiempirical Calculations

The PE spectra of the 3,5-dihydro-4H-1,2,3-triazoles 1-3 have been recorded.The ionization potentials have been assigned to molecular orbitals on the basis of MNDO, AM1, and PM3 calculations.The most important occupied MOs are characterized as ?NNN, ?C=X (X = O, NCH3, CH2), nN-3, n+NN, n-NN and nX.The gas-phase thermolyses of 1-3 have been studied by PE-controlled real-time gas analysis.After extrusion of molecular nitrogen, the remaining reactive species cyclize to three-membered rings.At higher temperatures and in flash vacuum pyrolysis, subsequent reactions lead to smaller acyclic compounds. - Key Words: Electronic structure / Photoelectron spectroscopy / Gas-phase thermolysis / Pyrolysis / 4H-1,2,3-Triazoles, 3,5-dihydro- / Semiempirical MO calculations