83566-01-2

Upstream product

• 3638-64-0 1-nitroethylene 
• 2004-70-8 1-methylbuta-1,3-diene 
• 123-35-3 7-methyl-3-methene-1,6-octadiene 

Downstream Products

• 83566-03-4 {2-[4-(4-Methyl-pent-3-enyl)-1-nitro-cyclohex-3-enyl]-ethanesulfinyl}-benzene 
• 97764-19-7 3-[4-(4-Methyl-pent-3-enyl)-1-nitro-cyclohex-3-enyl]-propionic acid methyl ester 
• 97764-23-3 3-[4-(4-Methyl-pent-3-enyl)-cyclohex-3-enyl]-propionic acid methyl ester 
• 83566-05-6 {2-[4-(4-Methyl-pent-3-enyl)-cyclohex-3-enyl]-ethanesulfinyl}-benzene 
• 73301-20-9 1-(4-methyl-3-pentenyl)cyclohexene 

Relevant academic research and scientific papers

REGIOSELECTIVE DIELS-ALDER REACTIONS. THE NITRO GROUP AS A REGIOCHEMICAL CONTROL ELEMENT

The sequence of the Diels-Alder reaction of α-nitroalkenes with diens and subsequent denitration with Bu3SnH provides a new method for the regioselective construction of cyclohexene derivatives.

CONJUGATE ADDITION OF ALKYL GROUPS TO α,β-UNSATURATED SULFOXIDES VIA MICHAEL ADDITION OF NITROPARAFFINS AND SUBSEQUENT DENITRATION WITH TRIBUTYLTIN HYDRIDE

Michael addition of nitroparaffins to α,β-unsaturated sulfoxides is well effected in the presence of DBU.The nitro group in the adduct is replaced by hydrogen with Bu3SnH without influence to the sulfinyl function.The overall reactions provide an efficien