83566-61-4

Upstream product

• 83566-60-3 methyl 2,3,4,6-tetradeoxy-4-amino-3-C-methyl-3-benzyloxycarbonylamino-D-xylo-hexopyranoside 
• 79-22-1 methyl chloroformate 
• 83566-55-6 methyl 2,3,4,6-tetradeoxy-4-iodo-3-methoxycarbonylamino-3-C-methyl-β-DL-xylo-hexopiranoside 
• 83566-56-7 (1R,2S,4S,6R)-4-Methoxy-2,6-dimethyl-3-oxa-7-aza-bicyclo[4.1.0]heptane 
• 83566-54-5 (2S,3S,4R)-3-Iodo-4-isocyanato-6-methoxy-2,4-dimethyl-tetrahydro-pyran 
• 90191-66-5 2-methoxy-4,6-dimethyl-3,6-dihydro-2H-pyrane 
• 83566-60-3 ((2S,3S,4R,6S)-3-Amino-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-carbamic acid benzyl ester 
• 83566-55-6 methyl 2,3,4,6-tetradeoxy-4-iodo-3-methoxycarbonylamino-3-C-methyl-α-DL-xylo-hexapyranoside 
• 83566-56-7 (1R,2S,4R,6R)-4-Methoxy-2,6-dimethyl-3-oxa-7-aza-bicyclo[4.1.0]heptane 
• 83566-60-3 methyl 4-amino-3-benzyloxycarbonylamino-2,3,4,6-tetradeoxy-3-C-methyl-α-DL-xylo-hexopyranoside 
• 74995-85-0 Methyl-4-O-benzoyl-2,6-didesoxy-3-C-methyl-α-D-ribo-hexopyranosid 
• 83566-53-4 (2S,6R)-2-Methoxy-4,6-dimethyl-3,6-dihydro-2H-pyran 
• 83566-59-0 ((2R,3R,4S,6S)-3-Azido-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-carbamic acid benzyl ester 
• 83566-55-6 ((2R,3R,4S,6S)-3-Iodo-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-carbamic acid methyl ester 

Relevant academic research and scientific papers

Syntheses of Methyl α- and β-DL-Tetranitrosides (or Kijanosides)

Methyl α- and β-DL-2,3,4,6-tetradeoxy-4-(methoxycarbonylamino)-3-C-methyl-3-nitro-xylo-hexopyranosides (13a, b) were synthesized from methyl α- and β-DL-2,3,4,6-tetradeoxy-hex-3-enopyranosides (2).The key step in the syntheses involved regio- and stereosp

SYNTHESIS AND ABSOLUTE CONFIGURATION OF METHYL α-TETRONITROSIDE (KIJANOSIDE)

Synthesis of methyl α-D-tetronitroside (11) from D-mannose via methyl α-D-mycaroside (1) established the D-configuration for tetronitrose(=kijanose), a novel nitro sugar which occurs as a component of the antitumor antibiotics tetrocarcins A and B, and kijanimicin.