83571-87-3Relevant academic research and scientific papers
Multiple Methylene Insertion Reactions: the Crystal Structure of a Complex formed by Insertion of Methylene into a Pt-P Bond
Azam, Kazi A.,Frew, Aileen A.,Lloyd, Brian R.,Manojlovic-Muir, Ljubica,Muir, Kenneth W.,Puddephatt, Richard J.
, p. 614 - 616 (1982)
Up to three methylene groups from diazomethane may be incorporated into hydridodiplatinum(I) complexes by insertion into Pt-Pt, Pt-H and,in one case, a Pt-P bond; X-ray structure determination establishes the existence of an ylide-(μ-methylene) complex of platinum, and the first details of the geometry of an M2(μ-CH2) group with no M-M bond are reported.
