83577-41-7Relevant academic research and scientific papers
CARBON-ALKYLATION, ARYLATION AND VINYLATION OF NITRONATE IONS WITH ORGANOTHALLIUM(III) COMPOUNDS: ELECTRON-TRANSFER ACTIVATION OF THE Tl-C BOND
Kurosawa, Hideo,Sato, Masahiro,Okada, Hiroshi
, p. 2965 - 2968 (2007/10/02)
The reaction of alkyl, aryl and vinylthallium(III) diacetates with nitronate ions gives moderate to good yields of the carbon-carbon bonded products.The reaction of the alkyl and arylthallium(III) analogs proceeds through radical intermediates which are generated by electron-transfer activation of the thallium-carbon bond.
