83577-70-2Relevant academic research and scientific papers
A METHOD FOR METHYLIDENATION AND ETHYLIDENATION OF AN ALLYLIC THIOETHER LEADING TO A 2,3-SIGMATROPIC REARRANGEMENT. FAILURE OF THE SIMMONS-SMITH REACTION IN THE PRESENCE OF THIOETHERS
Kosarych, Zenyk,Cohen, Theodore
, p. 3019 - 3022 (2007/10/02)
Allylic phenylthioethers are converted in one step to homoallylic phenylthioethers by treatment with methylene iodide or ethylidene iodide in the presence of diethylzinc but not zinc-copper or zinc-silver couples; furthermore, Simmons-Smith cyclopropanati
