835883-35-7

Upstream product

• 167103-03-9 4-methoxy-3-methyl-2-phenylaniline 
• 156048-12-3 6-Bromo-3-ethoxycarbonyloxy-2-methyl-1-phenyl-carbazole-9-carboxylic acid ethyl ester 
• 156048-02-1 3-Ethoxycarbonyloxy-2-methyl-1-phenyl-carbazole-9-carboxylic acid ethyl ester 
• 156048-19-0 6-Bromo-3-hydroxy-2-methyl-1-phenyl-carbazole-9-carboxylic acid ethyl ester 
• 835883-30-2 trifluoro-methanesulfonic acid 3-methoxy-2-methyl-6-nitro-phenyl ester 
• 5673-07-4 2,6-dimethoxytoluene 
• 38226-14-1 3-methoxy-2-methyl-6-nitrophenol 
• 157143-37-8 6-Bromo-3-methoxy-2-methyl-1-phenyl-carbazole-9-carboxylic acid ethyl ester 

Downstream Products

• 74364-10-6 6-chloro-3-methoxy-2-methyl-1-phenyl-9H-carbazole 

Relevant academic research and scientific papers

Transition metal complexes in organic synthesis, part 74: Total synthesis of the marine alkaloid 6-chlorohyellazole

A considerably improved iron-mediated synthesis leads to the marine carbazole alkaloid hyellazole on large scale in eight steps and 63% overall yield from 2,6-dimethoxytoluene. The first conversion of hyellazole into 6-chlorohyellazole has been achieved a

Synthesis of the Carbazole Alkaloids Hyellazole and 6-Chlorohyellazole and Related Derivatives

We described a new seven-stage synthesis of the carbazole alkaloids hyellazole and 6-chlorohyellazole, which proceeds via thermal cyclization of the 3-(buta-1,3-dienyl)indoles 7ab and 7bb, prepared from the condensation products of indole-2,3-diones 1a, b and the 3-methyl-4-phenylbut-3-en-2-one 2b.This procedure was also used to prepare related 3-methoxy-1-phenylcarbazole derivatives.