83605-30-5

Upstream product

• 52755-39-2 (2E)-1-phenylbut-2-en-1-ol 
• 74-88-4 methyl iodide 

Downstream Products

• 148586-83-8 (E)-2,2-Dimethyl-5-phenyl-oct-6-en-3-one 
• 148586-82-7 (E)-2,2,5-Trimethyl-7-phenyl-hept-6-en-3-one 
• 118622-70-1 2-((Z)-1-Benzyl-2-methyl-4-phenyl-but-3-enylidene)-[1,3]dithiolane 
• 118622-69-8 2-((E)-1-Benzyl-2-phenyl-pent-3-enylidene)-[1,3]dithiolane 
• 112573-95-2 (E)-(3-methylhexa-1,5-dien-1-yl)benzene 

Relevant academic research and scientific papers

Efficient assembly of α-aryl and α-vinyl nitriles via iron-catalyzed ether bond activation

A novel and practical method for the synthesis of diverse α-aryl and α-vinyl nitriles was developed via an iron-catalyzed sp3 C-O ether bond cleavage with C-C bond formation in the reaction of π-activated ethers with TMSCN.

Iron-catalyzed π-activated C-O ether bond cleavage with C-C and C-H bond formation

A novel and efficient allylic alkylation reaction between π-activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed C sp 3-O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp3-sp3 C-C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent. A mild, economical, and environmentally friendly method for the construction of C sp 3-C sp 3 bonds through iron-catalyzed π-activated C-O ether bond cleavage is developed. In addition, this catalytic system can be used for the selective reduction of benzylic and allylic C-O ether bonds to C-H bonds. Copyright

Efficient assembly of α-aryl and α-vinyl nitriles via iron-catalyzed ether bond activation

A novel and practical method for the synthesis of diverse α-aryl and α-vinyl nitriles was developed via an iron-catalyzed sp3 C-O ether bond cleavage with C-C bond formation in the reaction of π-activated ethers with TMSCN.

Iron-Catalyzed π-Activated C-O Ether Bond Cleavage with C-C and C-H Bond Formation

A novel and efficient allylic alkylation reaction between π-activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed C sp 3-O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp3-sp3 C-C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent.