83610-88-2Relevant academic research and scientific papers
The exchange reaction of hydrogen atoms in the system sterically hindered hydroxylamine - Nitroxyl radical
Malievskii,Koroteev
, p. 1287 - 1291 (1998)
The rate constants of the direct and reverse exchange reactions of the hydrogen atom in the system sterically-hindered nitroxyl radical - hydroxylamine of the quinoline, imidazoline, pyrrolidine, and piperidine series as well as diarylhydroxylamine were determined. A scale of the reductive abilities of the hydroxylamines was established. A low value of the isotope effect is typical of the reactions of hydrogen exchange in the systems hydroxylamine - nitroxyl radical.
