83622-84-8Relevant academic research and scientific papers
Approaches to new water soluble phosphines
Mitchell, Terence N.,Heesche-Wagner, Kerstin
, p. 43 - 53 (2007/10/02)
Approaches to water-soluble phosphines are described which involve conversion of ethylene glycol derivatives and sugar diacetonides into monoallyl ethers, and hydrophosphorylation of the latter.In the case of the sugars, water-solubility is conferred by a subsequent hydrolysis.
TRANSITION METAL PHOSPHINE COMPLEXES POSSESING A PHASE TRANSFER FUNCTION. PREPARATION AND PROPERTIES OF POLYETHER-SUBSTITUED PHOSPHINES AND THEIR PALLADIUM COMPLEXES
Okano, Tamon,Yamamoto, Manabu,Noguchi, Takeo,Konishi, Hisatoshi
, p. 977 - 980 (2007/10/02)
For the purpose of endowing transition metal phosphine complexes with a phase transfer function, tertiary phosphines modified by polyether chains were prepared, and their properties were examined.The palladium complexes of these phosphines were efficient as catalysts for the reduction of bromobenzene with sodium hydride under a liquid-solid two-phase condition.
