83654-37-9Relevant academic research and scientific papers
FLUOROALIPHATIC ESTERS OF FLUOROSULFONIC ACID. 5. CONJUGATE RADICAL FLUOROSULFATOHALOGENATION OF HIGHER FLUOROOLEFINS
Rogovik, V. M.,Aerov, A. F.,Delyagina, N. I.,Cherstkov, V. F.,Sterlin, S. R.,German, L. S.
, p. 794 - 798 (2007/10/02)
A study has been made of the electrochemical fluorosulfatation of perfluoro-2-alkanes in the presence of halogens, leading to the formation of fluoroaliphatic vicinal fluorosulfatohalides.The reaction proceeds as a conjugate radical addition of peroxydisulfuryl difluoride and the halogen at the double bond of the olefin; the ratio of the resulting regioisomers is determined by steric factors. Keywords: electrolysis, fluorosulfatohalogenation, stable radical.
