83656-79-5Relevant articles and documents
Synthesis of Annulated Anthracenes, Carbazoles, and Thiophenes Involving Bradsher-Type Cyclodehydration or Cyclization-Reductive-Dehydration Reactions
Rafiq, Settu Muhamad,Sivasakthikumaran, Ramakrishnan,Karunakaran, Jayachandran,Mohanakrishnan, Arasambattu K.
, p. 5099 - 5114 (2015/08/18)
A conventional BF3·OEt2-mediated Bradsher-type cyclodehydration of 2-arylmethyl benzaldehydes in CH2Cl2 at room temperature gave polycyclic aromatic and heteroaromatic compounds. Alternatively, these compounds could be synthesized in better yields from 2-arylmethylbenzoic acids by triflic-acid-mediated cyclization followed by reductive dehydration.