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Palladium-catalysed Allylic Alkylation of Allylic Nitro Compounds with Stabilized Carbanions
Ono, Noburu,Hamamoto, Isami,Kaji, Aritsune
, p. 1439 - 1444 (2007/10/02)
In the presence of a catalytic amount of Pd(PPh3)4, allylic nitro compounds (1) undergo allylic alkylation with stabilized carbanions to give a mixture of two regio-isomers (2) and (3).The product ratio (2):(3) is controlled both by the nature of the subs
