83663-03-0

Upstream product

• 3006-58-4 2-carbobenzyloxyamino-2-deoxy-D-glucopyranose 
• 107-18-6 allyl alcohol 
• 1078691-95-8 (+)-D-glucosamine hydrochloride 
• 501-53-1 benzyl chloroformate 
• 77059-32-6 benzyl ((2S,3R,4R,5S,6R)-2,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)carbamate 

Downstream Products

• 128745-41-5 allyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranoside 
• 83663-00-7 C₃₁H₃₁NO₉ 
• 83663-01-8 C₃₂H₃₃NO₁₁S 
• 102689-55-4 propyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-α-D-glucopyranoside 
• 83663-02-9 ((1R,2R,4S,5R,6R)-4-Allyloxy-2-hydroxymethyl-3,7-dioxa-bicyclo[4.1.0]hept-5-yl)-carbamic acid benzyl ester 
• 128745-43-7 allyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-α-D-allopyranoside 
• 128745-48-2 2-amino-1,6-di-O-(tert-butyldiphenylsilyl)-2-N,3-O-carbonyl-2-deoxy-D-allitol 
• 128745-42-6 allyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-α-D-ribo-hexapyranosid-3-ulose 
• 128745-46-0 2-amino-6-O-(tert-butyldiphenylsilyl)-2-N,3-O-carbonyl-2-deoxy-α,β-D-allofuranose 
• 128745-47-1 2-amino-6-O-(tert-butyldiphenylsilyl)-2-N,3-O-carbonyl-deoxy-D-allitol 
• 128745-44-8 allyl 2-amino-4,6-O-benzylidene-2-N,3-O-carbonyl-2-deoxy-α-D-allopyranoside 
• 128745-45-9 1-propenyl 2-amino-4,6-O-benzylidene-2-N,3-O-carbonyl-2-deoxy-α-D-allopyranoside 

Relevant academic research and scientific papers

Regioselective sulfamoylation at low temperature enables concise syntheses of putative small molecule inhibitors of sulfatases

Regioselective sulfamoylation of primary hydroxyl groups enabled a 5-step synthesis (overall yield 17%) of the first reported small molecule inhibitor of sulfatase-1 and 2, ((2S,3R,4R,5S,6R)-4,5-dihydroxy-2-methoxy-6-((sulfamoyloxy)methyl)tetrahydro-2H-pyran-3-yl)sulfamic acid, which obviated the use of hydroxyl protecting groups and is a marked improvement on the reported 9-step synthesis (overall yield 9%) employing hazardous trifluoromethylsulfonyl azide. The sulfamoylation methodology was used to prepare a range of derivatives of 1, and inhibition data was generated for Sulf-2, ARSA and ARSB.

Chemical synthesis of N-acetylglucosamine derivatives and their use as glycosyl acceptors by the Mesorhizobium loti chitin oligosaccharide synthase NodC

Rhizobial bacteria synthesize lipo-chitin oligosaccharide signal molecules (Nod factors) that are essential for the formation of symbiotic organs on the roots of host plants, a process known as nodulation. Biosynthesis of the chitin oligosaccharide moiety

TOTAL SYNTHESIS OF ANTIBIOTIC STREPTOTHRICIN F

The first total synthesis of streptothricin F was achieved and its structure was unequivocally confirmed.