83670-47-7Relevant academic research and scientific papers
Method for synthesizing azanol
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Paragraph 0157; 0200; 0206, (2016/10/08)
The invention relates to a hydroxylamine synthesis method. The hydroxylamine synthesis method comprises the following steps: (A) enabling alcohol to react with alkyl sulfonyl halide in the presence of an acid-binding agent to obtain sulphonate; (B) enabling the obtained sulphonate in the step (A) to react with N-hydroxycyclodiimide in the presence of alkali to generate alkylate of the N-hydroxycyclodiimide; and (C) enabling the alkylate obtained in the step (B) to react with an aminolysis reagent or a hydrazinolysis reagent to obtain the hydroxylamine. The method is high in yield and suitable for large-scale industrial hydroxylamine synthesis.
ALKYLATION OF AMINOHYDROXY ANION, DISSOCIATED SPECIES OF HYDROXYLAMINE
Kashima, Choji,Yoshiwara, Nobutoshi,Omote, Yoshimori
, p. 2955 - 2956 (2007/10/02)
Aminohydroxy anion (3), dissociated species of hydroxylamine, was demontrated to be nucleophilic on oxygen atom from INDO calculation, and to give directly O-alkylhydroxylamines.
