83671-20-9Relevant academic research and scientific papers
METHOXYIMINO COMPOUNDS AND FUNGICIDE COMPOSITION COMPRISING SAME
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Page/Page column 17-18, (2009/07/17)
The present invention provides a methoxyimino compound, and a fungicide composition comprising same as an active ingredient. The methoxyimino compound of the present invention, which has an excellent antifungal activity against a wide spectrum of fungi even at a low application rate, can be used to protect various crops.
SmI2-mediated elimination reaction of trichloromethyl carbinols: A facile method to synthesize vinyl dichlorides
Li, Jian,Xu, Xiaoliang,Zhang, Yongmin
, p. 9349 - 9351 (2007/10/03)
Samarium diiodide-mediated elimination reaction provides a simple and general method to synthesize vinyl dichlorides from trichloromethyl carbinols directly in good to excellent yields.
Conversion of aromatic aldehydes into 1-aryl-2,2-dichloroethenes
Nenajdenko,Shastin,Korotchenko,Balenkova
, p. 1047 - 1050 (2007/10/03)
A new general one-pot preparative method for the synthesis of 1-aryl(hetaryl)-2,2-dichloroethenes from aldehydes was developed. The method involves successive conversions of the latter into hydrazones followed by treatment with carbon tetrachloride in the
Reductive Addition of Polyhalomethanes and Their Related Compounds to Aldehydes and 1,2-Elimination of the Coupling Products in a Pb/Al Bimetal Redox System
Tanaka, Hideo,Yamashita, Shiro,Yamanoue, Motoi,Torii, Sigeru
, p. 444 - 450 (2007/10/02)
A Pb/Al bimetal system was used to carry out reductive addition of tetrachloromethane, tetrabromomethane, bromotrichloromethane, trichloroacetamide, and trichloroacetonitrile to aldehydes.Subsequent 1,2-elimination of the halogen atom and hydroxyl group from the coupling products was also performed with the Pb/Al bimetal system.The technology was successfully applied to stereocontrolled syntheses of ethyl trans- and cis-3-(2,2-dihaloethenyl)-2,2-dimethylcyclopropanecarboxylates.
