83696-65-5Relevant academic research and scientific papers
Thioenamide Photochemistry
Couture, Axel,Dubiez, Regine,Lablache-Combier, Alain
, p. 842 - 843 (1982)
In contrast with their oxo-analogues, thioenamides undergo photochemical cyclization to yield isoquinolinethione derivatives which are easily converted into isoquinolones and tetrahydroisoquinolines by treatment with benzeneseleninic anhydride and EtO3BF4
ETUDE COMPARATIVE DE LA PHOTOREACTIVITE D'ENAMIDES ET DE THIOENAMIDS AROMATIQUES TERTIAIRES
Couture, A.,Dubiez, R.,Lablanche-Combier, A.
, p. 1835 - 1844 (2007/10/02)
Photolytic reactions of some simple aromatic enamides and thioenamides illustrate a novel example of the dramatic difference in the photochemical behaviour of carbonyl and thiocarbonyl compounds.In contrast with their oxo-analogues which are photoconverted into enaminoketones, thioenamides undergo photochemical cyclization to yield isoquinolinethione derivatives which can be easily convered into isoquinolones and tetrahydroisoquinolines.
