83698-85-5Relevant academic research and scientific papers
Isomeric intraconversion among penta- and hexacoordinate cyclic oxyphosphoranes via oxygen atom coordination
Chandrasekaran,Day, Roberta O.,Holmes, Robert R.
, p. 11434 - 11441 (1997)
The synthesis of a series of cyclic pentaoxyphosphoranes containing a sulfonyl group was carried out by the reaction of either P(OCH2CF3)3 or P(OPh)3 with the appropriate diol in an oxidative addition reaction:
Synthesis and properties of new types of sulfoxide- or sulfone-bridged Lewis acids
Ohba,Ito,Nagasawa,Sakurai
, p. 1071 - 1076 (2007/10/03)
A series of new types of sulfur-bridged Lewis acids were synthesized. The ligands that contained the sulfoxide or sulfone as the joint moieties of two phenols were found to quantitatively give Lewis acids. These obtained Lewis acids also have good discrimination properties of some epoxides. The reaction properties of the Lewis acids were studied using the rearrangement of the epoxides to carbonyl compounds.
