83706-38-1

Basic information

• Product Name: N-(2-pyridinyl)-S-methyl-S-phenylsulfoximine
• Synonyms: N-(2-pyridinyl)-S-methyl-S-phenylsulfoximine
• CAS NO: 83706-38-1
• Molecular Weight: 232.306
• Mol File: 83706-38-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(2-pyridinyl)-S-methyl-S-phenylsulfoximine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-pyridinyl)-S-methyl-S-phenylsulfoximine(83706-38-1)
• EPA Substance Registry System: N-(2-pyridinyl)-S-methyl-S-phenylsulfoximine(83706-38-1)

Safety Data

• Hazardous Substances Data: 83706-38-1(Hazardous Substances Data)

Upstream product

• 504-29-0 2-aminopyridine 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 100-68-5 methyl-phenyl-thioether 
• 110-86-1 pyridine 
• 694-59-7 pyridine N-oxide 
• 4381-25-3 S-methyl-S-phenylsulfoximine 
• 83706-17-6 N-(2-Pyridyl)benzenesulfinamide 
• 5029-67-4 2-iodopyridine 
• 917-54-4 methyllithium 
• 83706-30-3 N-(2-Pyridyl)benzenesulfonimidoyl Fluoride 

Relevant articles and documents

Efficient copper-catalyzed N-arylation of sulfoximines with aryl iodides and aryl bromides

Two simple and inexpensive systems for copper-catalyed N-arylations of sulfoximines with aryl bromides and aryl iodides have been developed. Using 10 mol % of a copper(I) salt in combination with 20 mol % of a 1,2-diamine and Cs2CO3 provides N-arylated sulfoximines in high yields. Various functional groups and heteroatoms are tolarated. The method is complementary to the known protocols for N-arylations of sulfoximines, which require stoichiometric quantities of copper salts or cost-intensive palladium/BINAP catalysts.

Preparation and Reactions of Sulfonimidoyl Fluorides

Sulfonimidoyl fluorides have been prepared for the first time by treatment of sulfonimidoyl chlorides with various sources of fluoride ion.Sulfonimidoyl chlorides are reduced to sulfinamides with alkyllithium reagents; however, the corresponding fluorides