83711-16-4

Upstream product

• 75-21-8 oxirane 
• 3561-67-9 bis(phenylthio)methane 
• 105961-88-4 methyl 3,3-bis(phenylmercapto)propanoate 
• 108-98-5 thiophenol 

Downstream Products

• 83711-17-5 3,3-bis(phenylthio)-1-propyl benzenesulfonate 
• 263565-61-3 3,3-bis(phenylthio)propyl 4-propylbenzoate 
• 263565-60-2 3,3-bis(phenylthio)propyl 3-phenylpropanoate 
• 70871-28-2 1,2-bis(phenylthio)-1-cyclobutene 
• 83711-18-6 3-iodo-1,1-bis(phenylthio)propane 
• 83711-07-3 1-(phenylthio)-2-((p-tert-butylphenyl)thio)cyclobutene 
• 83711-08-4 1,2-bis(p-tert-butylphenylthio)cyclobutene 
• 83711-06-2 1,1-bis(phenylthio)-4,4-bis((p-tert-butylphenyl)thio)butane 
• 103979-41-5 1,1-bis(phenylsulphonyl)-3-tosyloxypropane 
• 103979-47-1 1,1-bis(phenylsulphonyl)-3-pivaloyloxypropane 
• 242483-25-6 2-benzyl-3-phenyl-thiopropionic acid S-(3,3-bis-phenylsulfanyl-propyl) ester 
• 242483-20-1 octanethioic acid S-(3,3-bis-phenylsulfanyl-propyl) ester 
• 242483-21-2 4-phenyl-thiobutyric acid S-(3,3-bis-phenylsulfanyl-propyl) ester 
• 242483-24-5 cyclohexanecarbothioic acid S-(3,3-bis-phenylsulfanyl-propyl) ester 

Relevant academic research and scientific papers

Titanocene(II)-promoted olefination of ω,ω-bis(phenylthio)alkyl alkanoates. A new method for the preparation of ω-hydroxy ketones

Intramolecular olefination of esters having a thioacetal moiety was studied. The treatment of ω,ω-bis(phenylthio)alkyl alkanoates with Cp2Ti[P(OEt)3]2 and the following hydrolysis gave ω-hydroxy ketones in good yields. (C) 2000 Elsevier Science Ltd.

Titanocene(II)-promoted intramolecular olefination of thiol esters: A new route to substituted 2,3-dihydrothiophenes

The treatment of S-[3,3-bis(phenylthio)propyl] thioalkanoates with the low-valent titanium species Cp2Ti[P(OEt)3]2 in THF produced 5-substituted 2,3-dihydrothiophenes in good yields. These thiophene derivatives were found to be susceptible to photoirradiation and easily isomerized into 2-alkylidenetetrahydrothiophenes.

Generation, Some Synthetic Uses, and 1,2-Vinyl Rearrangements of Secondary and Tertiary Homoallyllithiums, Including Ring Contractions and A Ring Expansion. Remarkable Acceleration of the Rearrangement by an Oxyanionic Group

A very general preparative method for homoallyllithiums consists of reductive lithiation of homoallylithiums consists of reductive lithiation of homoallyl phenyl sulfides by lithium 4,4'-di-tert-butylbiphenylide.The sulfides can be prepared by a variety o

Carbenoid Anion Behavior of Dilithio Derivatives of Thioacetal Alcohols. Stereochemistry and Mechanism of Ring Closures by Oxyanion-Facilitated CH Bond Insertion

Like other lithio derivatives of thioacetals bearing a second anionic site, dilithio derivatives of 3,3-, 5,5-, and 6,6-bis(phenylthio) alcohols decompose at or below ambient temperature to yield products ascribable to carbenoid intermediates.The 5,5-deri