837368-27-1Relevant articles and documents
Boosting hydrogen evolution by using covalent frameworks of fluorinated cobalt porphyrins supported on carbon nanotubes
Xu, Gelun,Lei, Haitao,Zhou, Guojun,Zhang, Chaochao,Xie, Lisi,Zhang, Wei,Cao, Rui
supporting information, p. 12647 - 12650 (2019/10/28)
A cobalt(ii) tetrakis(2,3,5,6-tetrafluoro-4-ethynylphenyl)porphyrin (FCoP-H) was designed and synthesized. With carbon-nanotube-templated polymerization, covalent porphyrin frameworks using FCoP-H can be synthesized via the Hay-coupling. The resulting FCo
A convenient preparation of 2,3,5,6-tetrafluoro-4-iodo-benzaldehyde and its application in porphyrin synthesis
Leroy, Jacques,Sch?llhorn, Bernd,Syssa-Magalé, Jean-Laurent,Boubekeur, Kamal,Palvadeau, Pierre
, p. 1379 - 1382 (2007/10/03)
An efficient synthesis of 2,3,5,6-tetrafluoro-4-iodo-benzaldehyde (1) is presented. This new compound was readily obtained via iodination at low temperature of the lithio derivative of 2-(2,3,5,6-tetrafluoro-phenyl)-[1,3]dioxolane (4). The crystal structure of 1 consists of linear polymeric chains, with non-covalent O?I bonding as the directing interaction, responsible for the observed assembly. Aldehyde 1 is further employed in the synthesis of 5,10,15,20-tetrakis(pentafluorophenyl) porphyrin (6), a potential precursor of supramolecular assemblies.