83740-82-3Relevant academic research and scientific papers
Thiono and Dithio Esters, XXIX. Reactions of Diazo Compounds with Thiooxalates
Hartke, Klaus,Kumar, Arvind,Koester, Joachim,Henssen, Guenther,Kissel, Thomas,et al.
, p. 3096 - 3106 (2007/10/02)
Dimethyl tetrathiooxalate (I) reacts with all diazo compounds 2 investigated to form 1,3-dithioles 3 in high yield.Complex mixtures of products, however, are obtained from O,O-dimethyl dithiooxalate (6) and diazo compounds.The reactions of 6 with diazomethane, diazoethane, 2-diazopropane and diphenyldiazomethane were investigated more in detail.
