83781-93-5

Upstream product

• 89-95-2 2-methyl-benzyl alcohol 
• 83781-92-4 o-[(trimethylsilyl)methyl]benzyl trimethylsilyl ether 
• 57754-01-5 2-[(trimethylsilyl)methyl]benzyl alcohol 

Downstream Products

• 104330-71-4 1-(2-Trimethylsilanylmethyl-benzyl)-3,4-dihydro-isoquinoline; compound with perchloric acid 
• 104330-68-9 2-Methyl-1-[1-o-tolyl-meth-(Z)-ylidene]-1,2,3,4-tetrahydro-isoquinoline 
• 104330-69-0 1-(o-methylbenzyl)-3,4-dihydroisoquinoline 
• 104330-70-3 1-(o-((trimethylsilyl)methyl)benzyl)-3,4-dihydroisoquiniline 
• 104330-74-7 1-(o-((trimethylsilyl)methyl)benzyl)-2-methyl-3,4-dihydroisoquinolinium perchlorate 
• 73331-49-4 trimethylammonium chloride 

Relevant academic research and scientific papers

2-[(Trimethylsilyl)methyl]benzyl methanesulfonates: Useful precursors for the generation of o -quinodimethanes

2-[(Trimethylsilyl)methyl]benzyl methanesulfonates react with potassium fluoride in the presence of a catalytic amount of 18-crown-6 at room temperature to give o-quinodimethanes, which are trapped with electron-deficient olefins to afford [4+2] cycloadducts in good yields. Georg Thieme Verlag Stuttgart New York.

DIRADICAL CYCLIZATION METHODOLOGIES. MODEL STUDIES PROBING THE APPLICATION OF PHOTOINDUCED-ELECTRON TRANSFER PROCESSES IN SYNTHETIC ROUTES TO THE PROTOBERBERINE AND SPIROBENZYL ISOQUINOLINE ALKALOIDS

Model studies have demonstrated that diradical cyclization processes, promoted by excited state electron transfer-desilylation pathways, serve as novel methods for construction of ring systems found in members of the protoberberine and spirobenzyl isoquin