83801-48-3Relevant academic research and scientific papers
DARSTELLUNG UND EIGENSCHAFTEN VON UND REAKTIONEN MIT METALLHALTIGEN HETEROCYCLEN. XXV. SYNTHESE UND EIGENSCHAFTEN NEUER PLATINA- UND RHODACYCLOALKANE DURCH SUBSTITUTION UND OXIDATIVE ADDITION EINER C-Cl-BINDUNG
Lindner, Ekkehard,Bouachir, Faouzi,Fawzi, Riad,Huebner, Dieter
, p. 345 - 352 (2007/10/02)
The platinacyclopentane derivative (Cl) is formed by action of Cl(CH2)3PR2 on Pt(COD)2 in n-hexane via the not isolable Pt2 (R = C6H11) by oxidative addition of a C-Cl bond to platinum. (μ-ClRh(CO)2>2 reacts in benzene with Cl(CH2)3PR2 under partially CO substitution to give the stable intermediate Cl(OC)Rh2.In boiling toluene oxidative addition of a C-Cl bond to rhodium occurs under formation of the phospharhodacyclopentane Cl2(OC) (R = C6H5).The 31P-NMR spectra of the rhodium compound is characterized by an ABX system, that of the platinum by superposition of an ABX pattern with an AB spectrum.
